Achieving a goal considered nearly impossible, JILA physicists have chilled a gas of molecules to very low temperatures by adapting the familiar process by which a hot cup of coffee cools.
Evaporative cooling has long been used to cool atoms, at JILA and elsewhere, to extraordinarily low temperatures. The process was used at JILA in 1995 to create a then-new state of matter, the Bose-Einstein condensate (BEC) of rubidium atoms. The latest demonstration, reported in the Dec. 20, 2012, issue of Nature,* marks the first time evaporative cooling has been achieved with molecules—two different atoms bonded together.
JILA researchers cooled about 1 million hydroxyl radicals, each composed of one oxygen atom and one hydrogen atom (OH), from about 50 milliKelvin (mK) to 5 mK, five-thousandths of a degree above absolute zero. The 70-millisecond process also made the cloud 1,000 times denser and cooler. With just a tad more cooling to below 1 mK, the new method may enable advances in ultracold chemistry, quantum simulators to mimic poorly understood physical systems, and perhaps even a BEC made of highly reactive molecules.
The same JILA group previously used magnetic fields and lasers to chill molecules made of potassium and rubidium atoms to temperatures below 1 microKelvin.** But the new work demonstrates a more widely usable method for cooling molecules that is potentially applicable to a wide range of chemically interesting species.
"OH is a hugely important species for atmospheric and combustion dynamics," says JILA/NIST Fellow Jun Ye, the group leader. "It is one of the most prominently studied molecules in physical chemistry. Now with OH molecules entering the ultracold regime, in addition to potassium-rubidium molecules, a new era in physical chemistry will be upon us in the near future."
JILA is a joint institute of the National Institute of Standards and Technology (NIST) and the University of Colorado (CU) Boulder. The results are the first to be published from the first experiments conducted in JILA's new X-Wing, which opened earlier this year. JILA theorist John Bohn collaborated with Ye's group.
In evaporative cooling, particles with greater-than-average energy depart, leaving a cooler and denser system behind. Unlike coffee, however, the trapped hydroxyl molecules have to be tightly controlled and manipulated for the process to work. If too many particles react rather than just bounce off each other, they overheat the system. Until now, this was widely seen as a barrier to evaporative cooling of molecules. Molecules are more complicated than atoms in their energy structures and physical motions, making them far more difficult to control.
To achieve their landmark result, Ye's group developed a new type of trap that uses structured magnetic fields to contain the hydroxyl molecules, coupled with finely tuned electromagnetic pulses that tweak the molecules' energy states to make them either more or less susceptible to the trap. The system allows scientists not only to control the release of the hotter, more energetic molecules from the collection, but also to choose which locations within the trap are affected, and which molecular energies to cull. The result is an extremely fine level of control over the cooling system, gradually ejecting molecules that are physically deeper and relatively cooler than before.
JILA scientists say it appears feasible to cool OH molecules to even colder temperatures, perhaps to a point where all the molecules behave alike, forming the equivalent of a giant "super molecule." This would enable scientists to finally learn some of the elusive basics of how molecules interact and develop novel ways to control chemical reactions, potentially benefitting atmospheric and combustion science, among other fields.
The research was funded by the National Science Foundation, Department of Energy, Air Force Office of Scientific Research and NIST.
* B.K. Stuhl, M.T. Hummon, M. Yeo, G. Quéméner, J.L. Bohn and J. Ye. Evaporative cooling of the dipolar hydroxyl radical. Nature. Dec. 20, 2012.
National Institute of Standards and Technology (NIST): http://www.nist.gov
This press release was posted to serve as a topic for discussion. Please comment below. We try our best to only post press releases that are associated with peer reviewed scientific literature. Critical discussions of the research are appreciated. If you need help finding a link to the original article, please contact us on twitter or via e-mail.
One in five cancers may be caused when common chemicals – deemed safe on their own – blend lethally inside the human body, study reveals
Cosmologist Sean Carroll tackles a deceptively simple question: Why does time exist at all? The potential answers point to a surprising view of the nature of the universe, and our place in it.
We've known we need dark matter since the 1930s, but still haven't found it. The search can't go on forever
Discovery could eventually transform computers as well.
Polymer scientist Christopher Sakezles landed the biggest deal in the reality show’s history
A cleverly designed pipe that uses water's own energy to fight gravity could be used in miniaturised disease labs
A new sensor based on particles whizzing along optical fibres could monitor temperature and radiation in dangerous environments
NASA's InSight mission may be able to use seismic waves from meteorite strikes to probe the Red Planet's interior
Niels Bohr, with his model of the atom, led physics into the quantum era. In the last of this season’s Perimeter Institute public lectures, his grandson Vilhelm will talk about personality and his influences
Simulations of how bird flocks move collectively found that some can be too large for information to pass across the whole group, limiting the size of a flock